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Chapter 05 — Wastes from petroleum refining, natural gas purification and pyrolytic treatment of coal Non-Hazardous

EWC Code

05 07

Wastes from natural gas purification and transportation

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume

Moderate — dominated by spent amine solutions and elemental sulphur

Valorisation Range

Elemental sulphur €50–120/t; spent amine solutions require treatment

Primary Route

Amine reclaiming and regeneration

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Waste Classification

EWC 05 07 covers wastes from the removal of impurities (H₂S, CO₂, water, mercury, heavy hydrocarbons) from natural gas before transmission and liquefaction. Principal streams are spent amine (DEA/MEA/MDEA) solutions used for gas sweetening, sulphur compounds from Claus unit operations and pipeline pigging solids.

Sulphur-containing wastes (05 07 01* — mercury-containing) are hazardous. Spent amine solutions (05 07 02) contain degradation products, heat-stable salts and absorbed H₂S; they require amine reclaiming or incineration. Pipeline pigging residues contain hydrocarbons, scale and corrosion products and may be classified hazardous depending on composition.

EU gas processing has expanded with LNG import terminal growth. Claus process recovered sulphur (non-waste where meeting product specification) is the dominant valorisation route. Sulphuric acid producers and fertiliser manufacturers are primary receivers of elemental sulphur. The sector is subject to IED Large Combustion Plant provisions and offshore-specific OSPAR guidelines.

Typical Generators

LNG terminals
Gas processing and sweetening plants
Transmission pipeline operators

Disposal & Valorisation Routes

Established valorisation pathways for EWC 05 07, ranked by economic value and market depth. Amine reclaiming and regeneration is the primary route.

Amine reclaiming and regeneration

Primary

Spent amine solutions processed through reclaimer units to remove heat-stable salts and degradation products, returning clean amine to service. Reclaimer bottoms (concentrated salts and heavy compounds) sent for further treatment or hazardous waste disposal.

Sulphur recovery and sale

Secondary

Elemental sulphur from Claus process sold as product where meeting EN 1420 or fertiliser-grade specification. Sulphur below spec co-processed at sulphuric acid plants or blended into sulphur-extended asphalt.

High-temperature incineration

Backstop

Mercury-containing wastes (05 07 01*) and off-spec amine streams incinerated at permitted hazardous waste facilities with mercury capture and acid gas scrubbing. Residue characterised before disposal.

These are the established routes for EWC 05 07. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of gas

Gas processing operators manage amine reclaiming in-house or via specialist contractors

02
Manufacture of fertilisers and nitrogen compounds

Purchases recovered elemental sulphur for sulphuric acid and superphosphate production

03
Manufacture of refined petroleum products

Sulphuric acid alkylation units consume recovered sulphur

04
Treatment and disposal of hazardous waste

Handles mercury-containing wastes and off-spec amine streams

Source: NACE Rev.2 — Eurostat, 2008

Regulatory Context

Key legislative frameworks governing EWC 05 07 classification, transport, and treatment.

IED 2010/75/EU — Large Combustion Plants and Refineries

Gas processing above threshold capacity falls under IED. Sulphur recovery efficiency (≥99.5% for large units) is a BAT-AEL. Mercury emissions from purification processes subject to ELVs under the Large Combustion Plant BREF.

OSPAR Decision 2000/2 on offshore chemicals

Offshore gas processing discharges governed by OSPAR MARPOL provisions. Produced water treatment and pipeline pigging waste management require notification under OSPAR framework for North Sea operations.

Directive 2008/98/EC — Mercury waste tracking

Mercury-containing wastes (05 07 01*) subject to enhanced tracking requirements under the EU Mercury Regulation 2017/852. Disposal to mercury-specific cells in stabilised form only; export to non-EU countries for recovery prohibited since 2011.

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Industries That Use This Waste

Sectors that valorise EWC 05 07 as an input material or secondary raw material.

Explore EU waste flows — Waste Atlas

Visualise 17 years of E-PRTR industrial facility data. See how EWC 05 07 and related waste streams flow across European industries and sectors.

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Source: EUR-Lex Commission Decision 2000/532/EC · NACE Rev.2 — Eurostat 2008

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