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Chapter 05 — Wastes from petroleum refining, natural gas purification and pyrolytic treatment of coalSub-code of EWC 05 07 Non-Hazardous

EWC Code

06 06 03

Wastes containing sulphides other than those in 06 06 02

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume (EU)

Moderate — dominated by spent amine solutions and elemental sulphur

Valorisation Range

Elemental sulphur €50–120/t; spent amine solutions require treatment

Primary Route

Amine reclaiming and regeneration

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EWC 06 06 03 is a specific sub-code under EWC 05 07 — Wastes from natural gas purification and transportation. The classification guidance below applies to this waste stream.

EWC 05 07 covers wastes from the removal of impurities (H₂S, CO₂, water, mercury, heavy hydrocarbons) from natural gas before transmission and liquefaction. Principal streams are spent amine (DEA/MEA/MDEA) solutions used for gas sweetening, sulphur compounds from Claus unit operations and pipeline pigging solids.

Sulphur-containing wastes (05 07 01* — mercury-containing) are hazardous. Spent amine solutions (05 07 02) contain degradation products, heat-stable salts and absorbed H₂S; they require amine reclaiming or incineration. Pipeline pigging residues contain hydrocarbons, scale and corrosion products and may be classified hazardous depending on composition.

EU gas processing has expanded with LNG import terminal growth. Claus process recovered sulphur (non-waste where meeting product specification) is the dominant valorisation route. Sulphuric acid producers and fertiliser manufacturers are primary receivers of elemental sulphur. The sector is subject to IED Large Combustion Plant provisions and offshore-specific OSPAR guidelines.

Typical Generators

LNG terminals
Gas processing and sweetening plants
Transmission pipeline operators

Disposal & Valorisation Routes

Established valorisation pathways for EWC 06 06 03, ranked by economic value and market depth.

Amine reclaiming and regeneration

Primary

Spent amine solutions processed through reclaimer units to remove heat-stable salts and degradation products, returning clean amine to service. Reclaimer bottoms (concentrated salts and heavy compounds) sent for further treatment or hazardous waste disposal.

Sulphur recovery and sale

Secondary

Elemental sulphur from Claus process sold as product where meeting EN 1420 or fertiliser-grade specification. Sulphur below spec co-processed at sulphuric acid plants or blended into sulphur-extended asphalt.

High-temperature incineration

Backstop

Mercury-containing wastes (05 07 01*) and off-spec amine streams incinerated at permitted hazardous waste facilities with mercury capture and acid gas scrubbing. Residue characterised before disposal.

These are the established routes for EWC 06 06 03. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of gas

Gas processing operators manage amine reclaiming in-house or via specialist contractors

02
Manufacture of fertilisers and nitrogen compounds

Purchases recovered elemental sulphur for sulphuric acid and superphosphate production

03
Manufacture of refined petroleum products

Sulphuric acid alkylation units consume recovered sulphur

04
Treatment and disposal of hazardous waste

Handles mercury-containing wastes and off-spec amine streams

Industries That Use This Waste

Sectors that valorise EWC 06 06 03 as an input material or secondary raw material.

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