Hazard Class 6.1
Poisonous material (Division 6.1) is a material, other than a gas, known to be so toxic to humans as to afford a hazard to health during transportation, or presumed toxic to humans based on laboratory animal oral, dermal or inhalation toxicity data.
Source: 49 CFR 173.132 (eCFR).
| UN Number | Proper Shipping Name | Packing Group |
|---|---|---|
| UN1051 | Hydrogen cyanide, stabilized with less than 3 percent water | I |
| UN1092 | Acrolein, stabilized | I |
| UN1098 | Allyl alcohol | I |
| UN1135 | Ethylene chlorohydrin | I |
| UN1143 | Crotonaldehyde or Crotonaldehyde, stabilized | I |
| UN1163 | Dimethylhydrazine, unsymmetrical | I |
| UN1181 | Ethyl chloroacetate | II |
| UN1182 | Ethyl chloroformate | I |
| UN1185 | Ethyleneimine, stabilized | I |
| UN1199 | Furaldehydes | II |
| UN1238 | Methyl chloroformate | I |
| UN1239 | Methyl chloromethyl ether | I |
| UN1244 | Methylhydrazine | I |
| UN1251 | Methyl vinyl ketone, stabilized | I |
| UN1259 | Nickel carbonyl | I |
| UN1510 | Tetranitromethane | I |
| UN1541 | Acetone cyanohydrin, stabilized | I |
| UN1544 | Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous | I, II, III |
| UN1545 | Allyl isothiocyanate, stabilized | II |
| UN1546 | Ammonium arsenate | II |
| UN1547 | Aniline | II |
| UN1548 | Aniline hydrochloride | III |
| UN1549 | Antimony compounds, inorganic, solid, n.o.s | III |
| UN1550 | Antimony lactate | III |
| UN1551 | Antimony potassium tartrate | III |
| UN1553 | Arsenic acid, liquid | I |
| UN1554 | Arsenic acid, solid | II |
| UN1555 | Arsenic bromide | II |
| UN1556 | Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s | I, II, III |
| UN1557 | Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s | I, II, III |
| UN1558 | Arsenic | II |
| UN1559 | Arsenic pentoxide | II |
| UN1560 | Arsenic trichloride | I |
| UN1561 | Arsenic trioxide | II |
| UN1562 | Arsenical dust | II |
| UN1564 | Barium compounds, n.o.s | II, III |
| UN1565 | Barium cyanide | I |
| UN1566 | Beryllium compounds, n.o.s | II, III |
| UN1567 | Beryllium, powder | II |
| UN1569 | Bromoacetone | II |
| UN1570 | Brucine | I |
| UN1572 | Cacodylic acid | II |
| UN1573 | Calcium arsenate | II |
| UN1574 | Calcium arsenate and calcium arsenite, mixtures, solid | II |
| UN1575 | Calcium cyanide | I |
| UN1577 | Chlorodinitrobenzenes, liquid. | II |
| UN1578 | Chloronitrobenzenes, solid | II |
| UN1579 | 4-Chloro-o-toluidine hydrochloride, solid | III |
| UN1580 | Chloropicrin | I |
| UN1583 | Chloropicrin mixtures, n.o.s | I, II, III |
| UN1585 | Copper acetoarsenite | II |
| UN1586 | Copper arsenite | II |
| UN1587 | Copper cyanide | II |
| UN1588 | Cyanides, inorganic, solid, n.o.s. | I, II, III |
| UN1590 | Dichloroanilines, liquid | II |
| UN1591 | o-Dichlorobenzene | III |
| UN1593 | Dichloromethane | III |
| UN1594 | Diethyl sulfate | II |
| UN1595 | Dimethyl sulfate | I |
| UN1596 | Dinitroanilines | II |
| UN1597 | Dinitrobenzenes, liquid | II, III |
| UN1598 | Dinitro-o-cresol | II |
| UN1599 | Dinitrophenol solutions | II, III |
| UN1600 | Dinitrotoluenes, molten | II |
| UN1601 | Disinfectants, solid, toxic, n.o.s. | I, II, III |
| UN1602 | Dyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic, n.o.s. | I, II, III |
| UN1603 | Ethyl bromoacetate | II |
| UN1605 | Ethylene dibromide | I |
| UN1606 | Ferric arsenate | II |
| UN1607 | Ferric arsenite | II |
| UN1608 | Ferrous arsenate | II |
| UN1611 | Hexaethyl tetraphosphate, liquid | II |
| UN1613 | Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, aqueous solutions with not more than 20 percent hydrogen cyanide | I |
| UN1614 | Hydrogen cyanide, stabilized, with less than 3 percent water and absorbed in a porous inert material | I |
| UN1616 | Lead acetate | III |
| UN1617 | Lead arsenates | II |
| UN1618 | Lead arsenites | II |
| UN1620 | Lead cyanide | II |
| UN1621 | London purple | II |
| UN1622 | Magnesium arsenate | II |
| UN1623 | Mercuric arsenate | II |
| UN1624 | Mercuric chloride | II |
| UN1625 | Mercuric nitrate | II |
| UN1626 | Mercuric potassium cyanide | I |
| UN1627 | Mercurous nitrate | II |
| UN1629 | Mercury acetate | II |
| UN1630 | Mercury ammonium chloride | II |
| UN1631 | Mercury benzoate | II |
| UN1634 | Mercury bromides | II |
| UN1636 | Mercury cyanide | II |
| UN1637 | Mercury gluconate | II |
| UN1638 | Mercury iodide | II |
| UN1639 | Mercury nucleate | II |
| UN1640 | Mercury oleate | II |
| UN1641 | Mercury oxide | II |
| UN1642 | Mercury oxycyanide, desensitized | II |
| UN1643 | Mercury potassium iodide | II |
| UN1644 | Mercury salicylate | II |
| UN1645 | Mercury sulfates | II |
| UN1646 | Mercury thiocyanate | II |
| UN1647 | Methyl bromide and ethylene dibromide mixtures, liquid | I |
| UN1649 | Motor fuel anti-knock mixtures | I |
| UN1650 | beta-Naphthylamine, solid | II |
| UN1651 | Naphthylthiourea | II |
| UN1652 | Naphthylurea | II |
| UN1653 | Nickel cyanide | II |
| UN1654 | Nicotine | II |
| UN1655 | Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s. | I, II, III |
| UN1656 | Nicotine hydrochloride liquid or solution | II, III |
| UN1657 | Nicotine salicylate | II |
| UN1658 | Nicotine sulfate solution | II, III |
| UN1659 | Nicotine tartrate | II |
| UN1661 | Nitroanilines ( o-; m-; p-; ) | II |
| UN1662 | Nitrobenzene | II |
| UN1663 | Nitrophenols ( o-; m-; p-; ) | III |
| UN1664 | Nitrotoluenes, liquid | II |
| UN1665 | Nitroxylenes, liquid | II |
| UN1669 | Pentachloroethane | II |
| UN1670 | Perchloromethyl mercaptan | I |
| UN1671 | Phenol, solid | II |
| UN1672 | Phenylcarbylamine chloride | I |
| UN1673 | Phenylenediamines (o-; m-; p-;) | III |
| UN1674 | Phenylmercuric acetate | II |
| UN1677 | Potassium arsenate | II |
| UN1678 | Potassium arsenite | II |
| UN1679 | Potassium cuprocyanide | II |
| UN1680 | Potassium cyanide, solid | I |
| UN1683 | Silver arsenite | II |
| UN1684 | Silver cyanide | II |
| UN1685 | Sodium arsenate | II |
| UN1686 | Sodium arsenite, aqueous solutions | II, III |
| UN1687 | Sodium azide | II |
| UN1688 | Sodium cacodylate | II |
| UN1689 | Sodium cyanide, solid | I |
| UN1690 | Sodium fluoride, solid | III |
| UN1691 | Strontium arsenite | II |
| UN1692 | Strychnine or Strychnine salts | I |
| UN1693 | Tear gas substances, liquid, n.o.s | I, II |
| UN1694 | Bromobenzyl cyanides, liquid | I |
| UN1695 | Chloroacetone, stabilized | I |
| UN1697 | Chloroacetophenone, solid, (CN) | II |
| UN1698 | Diphenylamine chloroarsine | I |
| UN1699 | Diphenylchloroarsine, liquid | I |
| UN1700 | Tear gas candles | — |
| UN1701 | Xylyl bromide, liquid | II |
| UN1702 | 1,1,2,2-Tetrachloroethane | II |
| UN1704 | Tetraethyl dithiopyrophosphate | II |
| UN1707 | Thallium compounds, n.o.s | II |
| UN1708 | Toluidines, liquid | II |
| UN1709 | 2,4-Toluylenediamine, solid or 2,4-Toluenediamine, solid | III |
| UN1710 | Trichloroethylene | III |
| UN1711 | Xylidines, liquid | II |
| UN1712 | Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc arsenite mixtures | II |
| UN1713 | Zinc cyanide | I |
| UN1722 | Allyl chloroformate | I |
| UN1737 | Benzyl bromide | II |
| UN1738 | Benzyl chloride | II |
| UN1750 | Chloroacetic acid, solution | II |
| UN1751 | Chloroacetic acid, solid | II |
| UN1752 | Chloroacetyl chloride | I |
| UN1809 | Phosphorus trichloride | I |
| UN1810 | Phosphorus oxychloride | I |
| UN1812 | Potassium fluoride, solid | III |
| UN1834 | Sulfuryl chloride | I |
| UN1838 | Titanium tetrachloride | I |
| UN1843 | Ammonium dinitro-o-cresolate, solid | II |
| UN1846 | Carbon tetrachloride | II |
| UN1851 | Medicine, liquid, toxic, n.o.s | II, III |
| UN1884 | Barium oxide | III |
| UN1885 | Benzidine | II |
| UN1886 | Benzylidene chloride | II |
| UN1887 | Bromochloromethane | III |
| UN1888 | Chloroform | III |
| UN1889 | Cyanogen bromide | I |
| UN1892 | Ethyldichloroarsine | I |
| UN1894 | Phenylmercuric hydroxide | II |
| UN1895 | Phenylmercuric nitrate | II |
| UN1897 | Tetrachloroethylene | III |
| UN1916 | 2,2′-Dichlorodiethyl ether | II |
| UN1935 | Cyanide solutions, n.o.s. | I, II, III |
| UN1994 | Iron pentacarbonyl | I |
| UN2016 | Ammunition, toxic, non-explosive, without burster or expelling charge, non-fuzed | — |
| UN2017 | Ammunition, tear-producing, non-explosive, without burster or expelling charge, non-fuzed | — |
| UN2018 | Chloroanilines, solid | II |
| UN2019 | Chloroanilines, liquid | II |
| UN2020 | Chlorophenols, solid | III |
| UN2021 | Chlorophenols, liquid | III |
| UN2022 | Cresylic acid | II |
| UN2023 | Epichlorohydrin | II |
| UN2024 | Mercury compound, liquid, n.o.s | I, II, III |
| UN2025 | Mercury compound, solid, n.o.s | I, II, III |
| UN2026 | Phenylmercuric compounds, n.o.s. | I, II, III |
| UN2027 | Sodium arsenite, solid | II |
| UN2038 | Dinitrotoluenes, liquid | II |
| UN2074 | Acrylamide, solid | III |
| UN2075 | Chloral, anhydrous, stabilized | II |
| UN2076 | Cresols, liquid | II |
| UN2077 | alpha-Naphthylamine | III |
| UN2078 | Toluene diisocyanate | II |
| UN2205 | Adiponitrile | III |
| UN2206 | Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C | II, III |
| UN2224 | Benzonitrile | II |
| UN2232 | 2-Chloroethanal | I |
| UN2233 | Chloroanisidines | III |
| UN2235 | Chlorobenzyl chlorides, liquid | III |
| UN2236 | 3-Chloro-4-methylphenyl isocyanate, liquid | II |
| UN2237 | Chloronitroanilines | III |
| UN2239 | Chlorotoluidines, solid | III |
| UN2249 | Dichlorodimethyl ether, symmetrical | I |
| UN2250 | Dichlorophenyl isocyanates | II |
| UN2253 | N,N-Dimethylaniline | II |
| UN2261 | Xylenols, solid | II |
| UN2267 | Dimethyl thiophosphoryl chloride | II |
| UN2272 | N-Ethylaniline | III |
| UN2273 | 2-Ethylaniline | III |
| UN2274 | N-Ethyl-N-benzylaniline | III |
| UN2279 | Hexachlorobutadiene | III |
| UN2281 | Hexamethylene diisocyanate | II |
| UN2285 | Isocyanatobenzotrifluorides | II |
| UN2290 | Isophorone diisocyanate | III |
| UN2291 | Lead compounds, soluble, n.o.s | III |
| UN2294 | N-Methylaniline | III |
| UN2295 | Methyl chloroacetate | I |
| UN2299 | Methyl dichloroacetate | III |
| UN2300 | 2-Methyl-5-ethylpyridine | III |
| UN2306 | Nitrobenzotrifluorides, liquid | II |
| UN2307 | 3-Nitro-4-chlorobenzotrifluoride | II |
| UN2311 | Phenetidines | III |
| UN2312 | Phenol, molten | II |
| UN2316 | Sodium cuprocyanide, solid | I |
| UN2317 | Sodium cuprocyanide, solution | I |
| UN2321 | Trichlorobenzenes, liquid | III |
| UN2322 | Trichlorobutene | II |
| UN2328 | Trimethylhexamethylene diisocyanate | III |
| UN2334 | Allylamine | I |
| UN2337 | Phenyl mercaptan | I |
| UN2382 | Dimethylhydrazine, symmetrical | I |
| UN2407 | Isopropyl chloroformate | I |
| UN2431 | Anisidines | III |
| UN2432 | N, N-Diethylaniline | III |
| UN2433 | Chloronitrotoluenes, liquid | III |
| UN2438 | Trimethylacetyl chloride | I |
| UN2446 | Nitrocresols, solid | III |
| UN2470 | Phenylacetonitrile, liquid | III |
| UN2471 | Osmium tetroxide | I |
| UN2473 | Sodium arsanilate | III |
| UN2474 | Thiophosgene | I |
| UN2477 | Methyl isothiocyanate | I |
| UN2480 | Methyl isocyanate | I |
| UN2481 | Ethyl isocyanate | I |
| UN2482 | n-Propyl isocyanate | I |
| UN2483 | Isopropyl isocyanate | I |
| UN2484 | tert-Butyl isocyanate | I |
| UN2485 | n-Butyl isocyanate | I |
| UN2486 | Isobutyl isocyanate | I |
| UN2487 | Phenyl isocyanate | I |
| UN2488 | Cyclohexyl isocyanate | I |
| UN2490 | Dichloroisopropyl ether | II |
| UN2501 | Tris-(1-aziridinyl)phosphine oxide, solution | II, III |
| UN2504 | Tetrabromoethane | III |
| UN2505 | Ammonium fluoride | III |
| UN2512 | Aminophenols ( o-; m-; p- ) | III |
| UN2515 | Bromoform | III |
| UN2516 | Carbon tetrabromide | III |
| UN2518 | 1,5,9-Cyclododecatriene | III |
| UN2521 | Diketene, stabilized | I |
| UN2522 | 2-Dimethylaminoethyl methacrylate, stabilized | II |
| UN2525 | Ethyl oxalate | III |
| UN2533 | Methyl trichloroacetate | III |
| UN2542 | Tributylamine | II |
| UN2552 | Hexafluoroacetone hydrate, liquid | II |
| UN2558 | Epibromohydrin | I |
| UN2567 | Sodium pentachlorophenate | II |
| UN2570 | Cadmium compounds | I, II, III |
| UN2572 | Phenylhydrazine | II |
| UN2574 | Tricresyl phosphate with more than 3 percent ortho isomer | II |
| UN2587 | Benzoquinone | II |
| UN2588 | Pesticides, solid, toxic, n.o.s. | I, II, III |
| UN2589 | Vinyl chloroacetate | II |
| UN2605 | Methoxymethyl isocyanate | I |
| UN2606 | Methyl orthosilicate | I |
| UN2609 | Triallyl borate | III |
| UN2611 | Propylene chlorohydrin | II |
| UN2628 | Potassium fluoroacetate | I |
| UN2629 | Sodium fluoroacetate | I |
| UN2630 | Selenates or Selenites | I |
| UN2642 | Fluoroacetic acid | I |
| UN2643 | Methyl bromoacetate | II |
| UN2644 | Methyl iodide | I |
| UN2645 | Phenacyl bromide | II |
| UN2646 | Hexachlorocyclopentadiene | I |
| UN2647 | Malononitrile | II |
| UN2648 | 1,2-Dibromobutan-3-one | II |
| UN2649 | 1,3-Dichloroacetone | II |
| UN2650 | 1,1-Dichloro-1-nitroethane | II |
| UN2651 | 4,4′-Diaminodiphenyl methane | III |
| UN2653 | Benzyl iodide | II |
| UN2655 | Potassium fluorosilicate | III |
| UN2656 | Quinoline | III |
| UN2657 | Selenium disulfide | II |
| UN2659 | Sodium chloroacetate | III |
| UN2660 | Nitrotoluidines (mono) | III |
| UN2661 | Hexachloroacetone | III |
| UN2664 | Dibromomethane | III |
| UN2667 | Butyltoluenes | III |
| UN2668 | Chloroacetonitrile | I |
| UN2669 | Chlorocresols solution | II, III |
| UN2671 | Aminopyridines (o-; m-; p-) | II |
| UN2673 | 2-Amino-4-chlorophenol | II |
| UN2674 | Sodium fluorosilicate | III |
| UN2688 | 1-Bromo-3-chloropropane | III |
| UN2689 | Glycerol alpha-monochlorohydrin | III |
| UN2690 | N-n-Butyl imidazole | II |
| UN2713 | Acridine | III |
| UN2716 | 1,4-Butynediol | III |
| UN2727 | Thallium nitrate | II |
| UN2729 | Hexachlorobenzene | III |
| UN2730 | Nitroanisole, liquid | III |
| UN2732 | Nitrobromobenzenes, liquid | III |
| UN2738 | N-Butylaniline | II |
| UN2740 | n-Propyl chloroformate | I |
| UN2742 | Chloroformates, toxic, corrosive, flammable, n.o.s | II |
| UN2743 | n-Butyl chloroformate | I |
| UN2744 | Cyclobutyl chloroformate | II |
| UN2745 | Chloromethyl chloroformate | II |
| UN2746 | Phenyl chloroformate | II |
| UN2747 | tert-Butylcyclohexylchloroformate | III |
| UN2748 | 2-Ethylhexyl chloroformate | II |
| UN2750 | 1,3-Dichloropropanol-2 | II |
| UN2753 | N-Ethylbenzyltoluidines liquid | III |
| UN2754 | N-Ethyltoluidines | II |
| UN2757 | Carbamate pesticides, solid, toxic | I, II, III |
| UN2759 | Arsenical pesticides, solid, toxic | I, II, III |
| UN2761 | Organochlorine pesticides, solid, toxic | I, II, III |
| UN2763 | Triazine pesticides, solid, toxic | I, II, III |
| UN2771 | Thiocarbamate pesticides, solid, toxic | I, II, III |
| UN2775 | Copper based pesticides, solid, toxic | I, II, III |
| UN2777 | Mercury based pesticides, solid, toxic | I, II, III |
| UN2779 | Substituted nitrophenol pesticides, solid, toxic | I, II, III |
| UN2781 | Bipyridilium pesticides, solid, toxic | I, II, III |
| UN2783 | Organophosphorus pesticides, solid, toxic | I, II, III |
| UN2785 | 4-Thiapentanal | III |
| UN2786 | Organotin pesticides, solid, toxic | I, II, III |
| UN2788 | Organotin compounds, liquid, n.o.s | I, II, III |
| UN2810 | Toxic, liquids, organic, n.o.s. | I, II, III |
| UN2811 | Toxic solids, organic, n.o.s. | I, II, III |
| UN2821 | Phenol solutions | II, III |
| UN2822 | 2-Chloropyridine | II |
| UN2831 | 1,1,1-Trichloroethane | III |
| UN2839 | Aldol | II |
| UN2849 | 3-Chloropropanol-1 | III |
| UN2853 | Magnesium fluorosilicate | III |
| UN2854 | Ammonium fluorosilicate | III |
| UN2855 | Zinc fluorosilicate | III |
| UN2856 | Fluorosilicates, n.o.s | III |
| UN2859 | Ammonium metavanadate | II |
| UN2861 | Ammonium polyvanadate | II |
| UN2862 | Vanadium pentoxide, non-fused form | III |
| UN2863 | Sodium ammonium vanadate | II |
| UN2864 | Potassium metavanadate | II |
| UN2871 | Antimony powder | III |
| UN2872 | Dibromochloropropane | II, III |
| UN2873 | Dibutylaminoethanol | III |
| UN2874 | Furfuryl alcohol | III |
| UN2875 | Hexachlorophene | III |
| UN2876 | Resorcinol | III |
| UN2902 | Pesticides, liquid, toxic, n.o.s. | I, II, III |
| UN2903 | Pesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C | I, II, III |
| UN2927 | Toxic liquids, corrosive, organic, n.o.s. | I, II |
| UN2928 | Toxic solids, corrosive, organic, n.o.s. | I, II |
| UN2929 | Toxic liquids, flammable, organic, n.o.s. | I, II |
| UN2930 | Toxic solids, flammable, organic, n.o.s. | I, II |
| UN2931 | Vanadyl sulfate | II |
| UN2936 | Thiolactic acid | II |
| UN2937 | alpha-Methylbenzyl alcohol, liquid | III |
| UN2941 | Fluoroanilines | III |
| UN2942 | 2-Trifluoromethylaniline | III |
| UN2946 | 2-Amino-5-diethylaminopentane | III |
| UN2948 | 3-Trifluoromethylaniline | II |
| UN2966 | Thioglycol | II |
| UN2991 | Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN2992 | Carbamate pesticides, liquid, toxic | I, II, III |
| UN2993 | Arsenical pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN2994 | Arsenical pesticides, liquid, toxic | I, II, III |
| UN2995 | Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN2996 | Organochlorine pesticides, liquid, toxic | I, II, III |
| UN2997 | Triazine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN2998 | Triazine pesticides, liquid, toxic | I, II, III |
| UN3002 | Phenyl urea pesticides, liquid, toxic | I, II, III |
| UN3005 | Thiocarbamate pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3006 | Thiocarbamate pesticide, liquid, toxic | I, II, III |
| UN3009 | Copper based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3010 | Copper based pesticides, liquid, toxic | I, II, III |
| UN3011 | Mercury based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3012 | Mercury based pesticides, liquid, toxic | I, II, III |
| UN3013 | Substituted nitrophenol pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3014 | Substituted nitrophenol pesticides, liquid, toxic | I, II, III |
| UN3015 | Bipyridilium pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3016 | Bipyridilium pesticides, liquid, toxic | I, II, III |
| UN3017 | Organophosphorus pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3018 | Organophosphorus pesticides, liquid, toxic | I, II, III |
| UN3019 | Organotin pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3020 | Organotin pesticides, liquid, toxic | I, II, III |
| UN3023 | 2-Methyl-2-heptanethiol | I |
| UN3025 | Coumarin derivative pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3026 | Coumarin derivative pesticides, liquid, toxic | I, II, III |
| UN3027 | Coumarin derivative pesticides, solid, toxic | I, II, III |
| UN3048 | Aluminum phosphide pesticides | I |
| UN3071 | Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan mixtures, liquid, toxic, flammable, n.o.s., flash point not less than 23 degrees C | II |
| UN3073 | Vinylpyridines, stabilized | II |
| UN3079 | Methacrylonitrile, stabilized | I |
| UN3080 | Isocyanates, toxic, flammable, n.o.s. or Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C | II |
| UN3086 | Toxic solids, oxidizing, n.o.s. | I, II |
| UN3122 | Toxic liquids, oxidizing, n.o.s. | I, II |
| UN3123 | Toxic liquids, water-reactive, n.o.s | I, II |
| UN3124 | Toxic solids, self-heating, n.o.s. | I, II |
| UN3125 | Toxic solids, water-reactive, n.o.s | I |
| UN3140 | Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. | I, II, III |
| UN3141 | Antimony compounds, inorganic, liquid, n.o.s | III |
| UN3142 | Disinfectants, liquid, toxic, n.o.s. | I, II, III |
| UN3143 | Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s. | I, II, III |
| UN3144 | Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s | I, II, III |
| UN3146 | Organotin compounds, solid, n.o.s. | I, II, III |
| UN3155 | Pentachlorophenol | II |
| UN3172 | Toxins, extracted from living sources, liquid, n.o.s | I, II, III |
| UN3243 | Solids containing toxic liquid, n.o.s. | II |
| UN3246 | Methanesulfonyl chloride | I |
| UN3249 | Medicine, solid, toxic, n.o.s | II, III |
| UN3250 | Chloroacetic acid, molten | II |
| UN3275 | Nitriles, toxic, flammable, n.o.s. | I, II |
| UN3276 | Nitriles, liquid, toxic, n.o.s. | I, II, III |
| UN3277 | Chloroformates, toxic, corrosive, n.o.s | II |
| UN3278 | Organophosphorus compound, liquid, toxic, n.o.s | I, II, III |
| UN3279 | Organophosphorus compound, toxic, flammable, n.o.s. | I, II |
| UN3280 | Organoarsenic compound, liquid, n.o.s. | I, II, III |
| UN3281 | Metal carbonyls, liquid, n.o.s. | I, II, III |
| UN3282 | Organometallic compound, liquid, toxic, n.o.s | I, II, III |
| UN3283 | Selenium compound, solid, n.o.s | I, II, III |
| UN3284 | Tellurium compound, n.o.s | I, II, III |
| UN3285 | Vanadium compound, n.o.s | I, II, III |
| UN3287 | Toxic liquid, inorganic, n.o.s | I, II, III |
| UN3288 | Toxic solid, inorganic, n.o.s. | I, II, III |
| UN3289 | Toxic liquid, corrosive, inorganic, n.o.s | I, II |
| UN3290 | Toxic solid, corrosive, inorganic, n.o.s | I, II |
| UN3293 | Hydrazine, aqueous solution, with not more than 37 percent hydrazine, by mass | III |
| UN3294 | Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide | I |
| UN3302 | 2-Dimethylaminoethyl acrylate, stabilized | II |
| UN3345 | Phenoxyacetic acid derivative pesticide, solid, toxic | I, II, III |
| UN3347 | Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3348 | Phenoxyacetic acid derivative pesticide, liquid, toxic | I, II, III |
| UN3349 | Pyrethroid pesticide, solid, toxic | I, II, III |
| UN3351 | Pyrethroid pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C | I, II, III |
| UN3352 | Pyrethroid pesticide, liquid toxic | I, II, III |
| UN3361 | Chlorosilanes, toxic, corrosive, n.o.s | II |
| UN3362 | Chlorosilanes, toxic, corrosive, flammable, n.o.s | II |
| UN3381 | Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3382 | Toxic by inhalation liquid, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3383 | Toxic by inhalation liquid, flammable, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3384 | Toxic by inhalation liquid, flammable, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3385 | Toxic by inhalation liquid, water-reactive, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3386 | Toxic by inhalation liquid, water-reactive, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3387 | Toxic by inhalation liquid, oxidizing, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3388 | Toxic by inhalation liquid, oxidizing, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3389 | Toxic by inhalation liquid, corrosive, n.o.s. with an LC50 lower than or equal to 200 ml/m 3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3390 | Toxic by inhalation liquid, corrosive, n.o.s. with an LC50 lower than or equal to 1000 ml/m 3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3409 | Chloronitrobenzenes, liquid | II |
| UN3410 | 4-Chloro-o-toluidine hydrochloride, solution | III |
| UN3411 | beta-Naphthylamine solution | II, III |
| UN3413 | Potassium cyanide solution | I, II, III |
| UN3414 | Sodium cyanide solution | I, II, III |
| UN3415 | Sodium fluoride solution | III |
| UN3416 | Chloroacetophenone, liquid, (CN) | II |
| UN3417 | Xylyl bromide, solid | II |
| UN3418 | 2,4-Toluylenediamine solution or 2,4-Toluenediamine solution | III |
| UN3422 | Potassium fluoride solution | III |
| UN3424 | Ammonium dinitro-o-cresolate solution | II, III |
| UN3426 | Acrylamide solution | III |
| UN3427 | Chlorobenzyl chlorides, solid | III |
| UN3428 | 3-Chloro-4-methylphenyl isocyanate, solid | II |
| UN3429 | Chlorotoluidines, liquid | III |
| UN3430 | Xylenols, liquid | II |
| UN3431 | Nitrobenzotrifluorides, solid | II |
| UN3434 | Nitrocresols, liquid | III |
| UN3436 | Hexafluoroacetone hydrate, solid | II |
| UN3437 | Chlorocresols, solid | II |
| UN3438 | alpha-Methylbenzyl alcohol, solid | III |
| UN3439 | Nitriles, solid, toxic, n.o.s. | I, II, III |
| UN3440 | Selenium compound, liquid, n.o.s | I, II, III |
| UN3441 | Chlorodinitrobenzenes, solid | II |
| UN3442 | Dichloroanilines, solid | II |
| UN3443 | Dinitrobenzenes, solid | II |
| UN3444 | Nicotine hydrochloride, solid | II |
| UN3445 | Nicotine sulphate, solid | II |
| UN3446 | Nitrotoluenes, solid | II |
| UN3447 | Nitroxylenes, solid | II |
| UN3448 | Tear gas substance, solid, n.o.s | I, II |
| UN3449 | Bromobenzyl cyanides, solid | I |
| UN3450 | Diphenylchloroarsine, solid | I |
| UN3451 | Toluidines, solid | II |
| UN3452 | Xylidines, solid | II |
| UN3454 | Dinitrotoluenes, solid | II |
| UN3455 | Cresols, solid | II |
| UN3457 | Chloronitrotoluenes, solid | III |
| UN3458 | Nitroanisoles, solid | III |
| UN3459 | Nitrobromobenzenes, solid | III |
| UN3460 | N-Ethylbenzyltoluidines, solid | III |
| UN3462 | Toxins, extracted from living sources, solid, n.o.s | I, II, III |
| UN3464 | Organophosphorus compound, solid, toxic, n.o.s | I, II, III |
| UN3465 | Organoarsenic compound, solid, n.o.s. | I, II, III |
| UN3466 | Metal carbonyls, solid, n.o.s. | I, II, III |
| UN3467 | Organometallic compound, solid, toxic, n.o.s | I, II, III |
| UN3483 | Motor fuel anti-knock mixture, flammable | I |
| UN3488 | Toxic by inhalation liquid, flammable, corrosive, n.o.s. with an LC50 lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3489 | Toxic by inhalation liquid, flammable, corrosive, n.o.s. with an LC50 lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3490 | Toxic by inhalation liquid, water-reactive, flammable, n.o.s. with an LC50 lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 | I |
| UN3491 | Toxic by inhalation liquid, water-reactive, flammable, n.o.s. with an LC50 lower or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 | I |
| UN3507 | Uranium hexafluoride, radioactive material, excepted package, less than 0.1 kg per package, non-fissile or fissile-excepted | I |
| UN3535 | Toxic solid, flammable, inorganic, n.o.s | I, II |
| UN3546 | Articles containing toxic substance, n.o.s. | — |
| UN3550 | Cobalt dihydroxide powder, containing not less than 10% respirable particles | I |
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