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HomeUN NumbersDivision 4.1 — Flammable Solid

Hazard Class 4.1

Division 4.1 — Flammable Solid

123 UN Numbers

Flammable solid (Division 4.1) covers desensitized explosives, self-reactive materials that are thermally unstable and can undergo exothermic decomposition without participation of oxygen, and readily combustible solids.

Source: 49 CFR 173.124 (eCFR).

UN NumberProper Shipping NamePacking Group
UN1309Aluminum powder, coatedII, III
UN1310Ammonium picrate, wetted with not less than 10 percent water, by massI
UN1312BorneolIII
UN1313Calcium resinateIII
UN1314Calcium resinate, fusedIII
UN1318Cobalt resinate, precipitatedIII
UN1320Dinitrophenol, wetted with not less than 15 percent water, by massI
UN1321Dinitrophenolates, wetted with not less than 15 percent water, by massI
UN1322Dinitroresorcinol, wetted with not less than 15 percent water, by massI
UN1323FerroceriumII
UN1324Films, nitrocellulose base, gelatine coated (except scrap)III
UN1325Flammable solids, organic, n.o.s.II, III
UN1326Hafnium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 micronsII
UN1328HexamethylenetetramineIII
UN1330Manganese resinateIII
UN1331Matches, strike anywhereIII
UN1332MetaldehydeIII
UN1333Cerium, slabs, ingots, or rodsII
UN1334Naphthalene, crude or Naphthalene, refinedIII
UN1336Nitroguanidine, wetted or Picrite, wetted with not less than 20 percent water, by massI
UN1337Nitrostarch, wetted with not less than 20 percent water, by massI
UN1338Phosphorus, amorphousIII
UN1339Phosphorus heptasulfide, free from yellow or white phosphorusII
UN1341Phosphorus sesquisulfide, free from yellow or white phosphorusII
UN1343Phosphorus trisulfide, free from yellow or white phosphorusII
UN1344Trinitrophenol, wetted with not less than 30 percent water, by massI
UN1345Rubber scrap or shoddy, powdered or granulated, not exceeding 840 microns and rubber contend exceeding 45%II
UN1346Silicon powder, amorphousIII
UN1347Silver picrate, wetted with not less than 30 percent water, by massI
UN1348Sodium dinitro-o-cresolate, wetted with not less than 15 percent water, by massI
UN1349Sodium picramate, wetted with not less than 20 percent water, by massI
UN1350SulfurIII
UN1352Titanium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 micronsII
UN1353Fibers or Fabrics impregnated with weakly nitrated nitrocellulose, n.o.sIII
UN1354Trinitrobenzene, wetted with not less than 30 percent water, by massI
UN1355Trinitrobenzoic acid, wetted with not less than 30 percent water, by massI
UN1356Trinitrotoluene, wetted or TNT, wetted, with not less than 30 percent water by massI
UN1357Urea nitrate, wetted with not less than 20 percent water, by massI
UN1358Zirconium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 micronsII
UN1437Zirconium hydrideII
UN1517Zirconium picramate, wetted with not less than 20 percent water, by massI
UN1571Barium azide, wetted with not less than 50 percent water, by massI
UN1868DecaboraneII
UN1869Magnesium or Magnesium alloys with more than 50 percent magnesium in pellets, turnings or ribbonsIII
UN1871Titanium hydrideII
UN1944Matches, safety (book, card or strike on box)III
UN1945Matches, wax, VestaIII
UN2000Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrapIII
UN2001Cobalt naphthenates, powderIII
UN2213ParaformaldehydeIII
UN2254Matches, fuseeIII
UN2304Naphthalene, moltenIII
UN2448Sulfur, moltenIII
UN2538NitronaphthaleneIII
UN2555Nitrocellulose with water with not less than 25 percent water, by massII
UN2556Nitrocellulose with alcohol with not less than 25 percent alcohol by mass, and with not more than 12.6 percent nitrogen, by dry massII
UN2557Nitrocellulose, with not more than 12.6 percent nitrogen, by dry mass mixture with or without plasticizer, with or without pigmentII
UN2623Firelighters, solid with flammable liquidIII
UN2687Dicyclohexylammonium nitriteIII
UN2714Zinc resinateIII
UN2715Aluminum resinateIII
UN2717Camphor, syntheticIII
UN2852Dipicryl sulfide, wetted with not less than 10 percent water, by massI
UN2858Zirconium, dry, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns)III
UN2878Titanium sponge granules or Titanium sponge powdersIII
UN2907Isosorbide dinitrate mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphateII
UN2925Flammable solids, corrosive, organic, n.o.s.II, III
UN2926Flammable solids, toxic, organic, n.o.s.II, III
UN29565-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xyleneIII
UN2989Lead phosphite, dibasicII, III
UN3089Metal powders, flammable, n.o.sII, III
UN3097Flammable solid, oxidizing, n.o.sII, III
UN3175Solids containing flammable liquid, n.o.s.II
UN3176Flammable solid, organic, molten, n.o.s.II, III
UN3178Flammable solid, inorganic, n.o.s.II, III
UN3179Flammable solid, toxic, inorganic, n.o.s.II, III
UN3180Flammable solid, corrosive, inorganic, n.o.s.II, III
UN3181Metal salts of organic compounds, flammable, n.o.sII, III
UN3182Metal hydrides, flammable, n.o.sII, III
UN3221Self-reactive liquid type B—
UN3222Self-reactive solid type B—
UN3223Self-reactive liquid type C—
UN3224Self-reactive solid type C—
UN3225Self-reactive liquid type D—
UN3226Self-reactive solid type D—
UN3227Self-reactive liquid type E—
UN3228Self-reactive solid type E—
UN3229Self-reactive liquid type F—
UN3230Self-reactive solid type F—
UN3231Self-reactive liquid type B, temperature controlled—
UN3232Self-reactive solid type B, temperature controlled—
UN3233Self-reactive liquid type C, temperature controlled—
UN3234Self-reactive solid type C, temperature controlled—
UN3235Self-reactive liquid type D, temperature controlled—
UN3236Self-reactive solid type D, temperature controlled—
UN3237Self-reactive liquid type E, temperature controlled—
UN3238Self-reactive solid type E, temperature controlled—
UN3239Self-reactive liquid type F, temperature controlled—
UN3240Self-reactive solid type F, temperature controlled—
UN32412-Bromo-2-nitropropane-1,3-diolIII
UN3242AzodicarbonamideII
UN3251Isosorbide-5-mononitrateIII
UN3270Nitrocellulose membrane filters, with not more than 12.6% nitrogen, by dry massII
UN33172-Amino-4,6-Dinitrophenol, wetted with not less than 20 percent water by massI
UN3319Nitroglycerin mixture, desensitized, solid, n.o.s. with more than 2 percent but not more than 10 percent nitroglycerin, by massII
UN3344Pentaerythrite tetranitrate mixture, desensitized, solid, n.o.s. or Pentaerythritol tetranitrate mixture, desensitized, solid, n.o.s. or PETN mixture, desensitized, solid, n.o.s., with more than 10 percent but not more than 20 percent PETN, by massII
UN3360Fibers, vegetable, dryIII
UN3364Trinitrophenol (picric acid), wetted, with not less than 10 percent water by massI
UN3365Trinitrochlorobenzene (picryl chloride), wetted, with not less than 10% water by massI
UN3366Trinitrotoluene (TNT), wetted, with not less than 10 percent water by massI
UN3367Trinitrobenzene, wetted, with not less than 10% water, by massI
UN3368Trinitrobenzoic acid, wetted with not less than 10% water by massI
UN3369Sodium dinitro-o-cresolate, wetted with not less than 10% water, by massI
UN3370Urea nitrate, wetted, with not less than 10 percent water by massI
UN33764-Nitrophenylhydrazine, with not less than 30 percent water, by massI
UN3380Desensitized explosive, solid, n.o.s.I
UN34741-Hydroxybenzotriazole, monohydrateI
UN3527Polyester resin kit, solid base material—
UN3531Polymerizing substance, solid, stabilized, n.o.s.III
UN3532Polymerizing substance, liquid, stabilized, n.o.s.III
UN3533Polymerizing substance, solid, temperature controlled, n.o.s.III
UN3534Polymerizing substance, liquid, temperature controlled, n.o.s.III
UN3541Articles containing flammable solid, n.o.s.—

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