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Chapter 06 — Wastes from inorganic chemical processes Non-Hazardous

EWC Code

06 05

Sludges from on-site effluent treatment

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume

~1–3 Mt/year sludge from inorganic chemical plant effluent treatment

Valorisation Range

Metal recovery from sludge €50–200/t; disposal cost €80–250/t hazardous landfill

Primary Route

Hydrometallurgical metal recovery

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Waste Classification

EWC 06 05 covers sludges arising from on-site physicochemical or biological treatment of process effluents at inorganic chemical facilities. Sub-code 06 05 02* (sludges from on-site effluent treatment containing dangerous substances) is hazardous; 06 05 03 covers non-hazardous sludge from the same source.

Sludge composition reflects the parent process — sulphate, chloride and metal hydroxide sludges from acid neutralisation; calcium fluoride sludge from HF neutralisation; chromium hydroxide sludge from chromate reduction and precipitation. Metal content determines whether the waste is hazardous under WFD Annex III property H14 (ecotoxic) or H6 (acute toxic).

Chemical oxygen demand (COD), total suspended solids (TSS) and specific heavy metal concentrations are measured to classify and route sludge. Dewatering (filter press, centrifuge) reduces volume before disposal. Where metal concentrations are economically viable, hydrometallurgical recovery is preferred. Non-hazardous calcium-bearing sludges may be suitable for cement kiln or agricultural use if composition is acceptable.

Typical Generators

Inorganic chemical manufacturers
Pigment production facilities
Electrochemical plants

Disposal & Valorisation Routes

Established valorisation pathways for EWC 06 05, ranked by economic value and market depth. Hydrometallurgical metal recovery is the primary route.

Hydrometallurgical metal recovery

Primary

Metal hydroxide sludges with significant Zn, Ni, Cu or Cr content processed through acid leach + SX/IX circuits to recover metal values. Residual stripped sludge re-tested; may qualify as non-hazardous after metal removal for landfill or co-processing.

Cement kiln co-processing

Secondary

Non-hazardous calcium sulphate and calcium fluoride sludges used as alternative raw material in cement clinker production. Fluoride acts as mineraliser, reducing kiln energy consumption. Acceptance limits: F ≤ 0.5% in feed; heavy metals checked against kiln operator permit.

Hazardous or inert landfill

Backstop

Hazardous sludges (06 05 02*) stabilised and disposed at hazardous landfill after WAC testing. Non-hazardous calcium carbonate sludges disposed at inert landfill. Dewatering to >30% dry solids typically required before acceptance.

These are the established routes for EWC 06 05. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of other inorganic basic chemicals

On-site effluent treatment generates sludge — metal recovery contractors collect for processing

02
Manufacture of cement

Accepts calcium fluoride and sulphate sludges as alternative raw materials and mineraliser

03
Copper production

Recovers copper and other base metals from metal hydroxide sludges

04
Treatment and disposal of hazardous waste

Stabilisation and landfill for non-recoverable hazardous sludge fractions

Source: NACE Rev.2 — Eurostat, 2008

Regulatory Context

Key legislative frameworks governing EWC 06 05 classification, transport, and treatment.

IED 2010/75/EU — Effluent treatment BAT

On-site effluent treatment at inorganic chemical IED installations must achieve BAT-associated emission levels. Sludge generation minimisation is BAT — closed-loop water recycling reduces sludge volumes. Annual sludge composition monitoring required.

Urban Wastewater Treatment Directive 91/271/EEC

Where inorganic chemical site effluent is discharged to municipal WWTP, pre-treatment requirements apply. Metal loading limits set by receiving WWTP permit to protect sludge quality for agricultural use.

Directive 2008/98/EC — Sludge classification

Hazardous/non-hazardous status determined by WFD Annex III properties tested on dewatered sludge. Mirror entries (06 05 02*/06 05 03) require waste producer assessment — self-classification with analytical evidence.

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Industries That Use This Waste

Sectors that valorise EWC 06 05 as an input material or secondary raw material.

Explore EU waste flows — Waste Atlas

Visualise 17 years of E-PRTR industrial facility data. See how EWC 06 05 and related waste streams flow across European industries and sectors.

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Source: EUR-Lex Commission Decision 2000/532/EC · NACE Rev.2 — Eurostat 2008

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