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Chapter 12 — Wastes from shaping and physical and mechanical surface treatment of metals and plastics Non-Hazardous

EWC Code

12 03

Wastes from water and steam degreasing processes

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume

2.8 million tonnes/year EU aqueous degreasing effluent

Valorisation Range

€95M aqueous degreasing waste treatment market

Primary Route

Emulsion breaking and oil recovery

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Waste Classification

Water and steam degreasing generates spent aqueous degreasing solution, oil-water emulsion, rinse water and filter cake as primary waste streams. Aqueous degreasing has replaced solvent degreasing on most industrial applications following restrictions on chlorinated solvents and VOC limits under Solvent Emissions Directive 1999/13/EC. Spent aqueous degreasing baths contain surfactants, emulsified oil, metal particles and corrosion inhibitors.

Alkaline aqueous degreasers operate at pH 10–13 using sodium hydroxide, silicates, phosphates and non-ionic surfactants to emulsify mineral and synthetic oils from machined components. Bath life is typically 4–12 weeks before contamination with oil, metal swarf and degraded surfactant necessitates replacement. Spent bath characterisation determines whether oils exceed hazardous classification thresholds.

Steam degreasing uses pressurised steam to remove light oils and particulates from complex geometry components, generating condensate containing oil and surfactant. Oil-water emulsions require emulsion breaking by acid dosing, centrifugation or ultrafiltration to separate oil phase (recycled or incinerated) from water phase (treated and discharged). Ultrafiltration permeate quality typically enables direct discharge to trade effluent after pH adjustment.

Typical Generators

Automotive component manufacturers
Metal parts manufacturers
Aerospace component processors
Consumer goods manufacturers
Electronics contract manufacturers

Disposal & Valorisation Routes

Established valorisation pathways for EWC 12 03, ranked by economic value and market depth. Emulsion breaking and oil recovery is the primary route.

Emulsion breaking and oil recovery

Primary

Spent degreasing emulsions are broken by acid dosing to pH 3–4 followed by centrifugation or dissolved air flotation to separate oil phase from water phase. Separated oil phase is sent to licensed waste oil processor or incineration with energy recovery. Water phase treated in wastewater plant before discharge to trade effluent.

Ultrafiltration membrane treatment

Secondary

Cross-flow ultrafiltration membranes separate oil and polymer emulsion from rinse water with >99% rejection. Permeate (90–95% of volume) achieves direct discharge quality (<50 mg/L oil). Concentrate (5–10% of volume) is thickened emulsion sent to licensed oil processor. Reduces hazardous waste volume by factor of 10–20 compared to bulk disposal.

Hazardous waste disposal for metal-contaminated concentrates

Backstop

Spent degreasing baths with elevated heavy metal content from metal dissolution (nickel, chromium from stainless steel) classified hazardous require disposal by licensed hazardous waste treatment operator. Chemical precipitation to remove metals followed by incineration with energy recovery. Filter cake from metals precipitation disposed to hazardous landfill.

These are the established routes for EWC 12 03. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Treatment and disposal of non-hazardous waste

Accept and treat aqueous degreasing waste through emulsion breaking and biological treatment

02
Manufacture of refined petroleum products

Accept separated oil phase from emulsion breaking for re-refining or blending

03
Treatment and coating of metals

Operate on-site ultrafiltration to reduce degreasing waste volume and recover water for reuse

04
Treatment and disposal of hazardous waste

Accept metal-contaminated degreasing concentrate for treatment and disposal

Source: NACE Rev.2 — Eurostat, 2008

Regulatory Context

Key legislative frameworks governing EWC 12 03 classification, transport, and treatment.

IED Annex VII (formerly SED 1999/13/EC) — VOC limits

Aqueous degreasing replaces solvent processes under VOC emission reduction requirements. Where residual VOC solvents remain in aqueous degreasing waste, waste characterisation must determine VOC content. Waste with >1% VOC classified as volatile waste for incineration purposes.

Urban Wastewater Treatment Directive 91/271/EEC — Trade effluent

Treated aqueous degreasing effluent discharged to sewer requires trade effluent consent specifying pH, oil, BOD, COD and suspended solids limits. Oil and grease limit for sewer discharge is typically 100–200 mg/L; direct discharge to watercourse typically <5 mg/L.

Directive 2008/98/EC — Waste oil hierarchy

Separated oil from emulsion breaking is subject to waste oil hierarchy under Article 21: regeneration (base oil recovery) preferred over energy recovery (incineration). Where oil contamination prevents regeneration (metal content >200 ppm), incineration with energy recovery is the highest available option.

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Industries That Use This Waste

Sectors that valorise EWC 12 03 as an input material or secondary raw material.

Explore EU waste flows — Waste Atlas

Visualise 17 years of E-PRTR industrial facility data. See how EWC 12 03 and related waste streams flow across European industries and sectors.

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Source: EUR-Lex Commission Decision 2000/532/EC · NACE Rev.2 — Eurostat 2008

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