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Chapter 07 — Wastes from organic chemical processes Non-Hazardous

EWC Code

07 07

Wastes from manufacture, formulation, supply and use of fine chemicals and chemical products not otherwise specified

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume

~500 kt–1 Mt/year fine chemical process waste

Valorisation Range

Solvent recovery €100–500/t; specialty chemical recovery up to €1000/t where feasible

Primary Route

Solvent recovery by distillation

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Waste Classification

EWC 07 07 is the catch-all for organic chemical process wastes not covered by 07 01 to 07 06 — it encompasses fine chemicals, specialty chemicals, flavours, fragrances, photographic chemicals (not 09 01), adhesive and resin intermediates, and chemical research by-products. Hazardous sub-codes parallel other 07 xx chapters: 07 07 01* (aqueous washing liquids), 07 07 03* (halogenated solvents), 07 07 07* (halogenated still bottoms), 07 07 08* (other still bottoms).

Fine chemical synthesis uses multi-step routes with multiple reagents, solvents and intermediate isolation steps — generating diverse, low-volume, highly contaminated waste streams. E-factors (waste kg per kg product) can reach 25–100, much higher than bulk chemical processes. Key challenges: complex mixed waste streams, small volumes that make dedicated recovery uneconomical, and highly variable composition requiring frequent waste characterisation.

Flavour and fragrance manufacture generates terpene-rich still bottoms (limonene, linalool), citrus extraction residues and essential oil decolouration carbon. These streams have potential as bio-based aromatic chemical feedstocks. CRO and toll synthesis facilities often operate across many different customer projects simultaneously, creating mixed waste classification challenges.

Typical Generators

Specialty and fine chemical producers
Flavour and fragrance manufacturers
Chemical synthesis CROs and toll manufacturers

Disposal & Valorisation Routes

Established valorisation pathways for EWC 07 07, ranked by economic value and market depth. Solvent recovery by distillation is the primary route.

Solvent recovery by distillation

Primary

Common solvents (ethanol, IPA, acetone, EtOAc, THF) from fine chemical synthesis separated by fractional distillation. Recovered solvents tested by GC purity analysis before reuse or sale. Third-party solvent recovery contractors accept mixed solvent streams for fractionation.

High-calorific waste fuel co-processing

Secondary

Non-halogenated still bottoms and mixed organic wastes with NCV >15 MJ/kg accepted by cement kilns or dedicated industrial energy-from-waste facilities. Waste characterisation analysis (GC/MS, metals, halogens) required before acceptance. Chlorine content limit typically 0.1–0.5% for cement kiln use.

Hazardous waste incineration

Backstop

Halogenated streams (07 07 03*, 07 07 07*) and wastes containing CMR substances incinerated at permitted high-temperature facilities. Small-volume drums from CRO/toll sites transported under ADR packing group requirements. Bulking of compatible streams reduces incineration cost.

These are the established routes for EWC 07 07. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of essential oils

Generates terpene still bottoms and essential oil residues

02
Manufacture of other chemical products

Fine chemical producers generate the majority of 07 07 waste — contracted to specialist hazardous waste managers

03
Manufacture of cement

Co-processes high-calorific organic chemical waste as alternative fuel

04
Treatment and disposal of hazardous waste

Handles diverse mixed hazardous waste from fine chemical and CRO facilities

Source: NACE Rev.2 — Eurostat, 2008

Regulatory Context

Key legislative frameworks governing EWC 07 07 classification, transport, and treatment.

IED 2010/75/EU — Organic chemicals BREF

Fine chemical plants above IED threshold (20,000 t/year of organic chemicals) require IED permit. Below threshold: national permitting applies. BAT for fine chemicals: solvent mass balance, closed process design, waste characterisation on generation and tracking.

REACH — Waste characterisation for mixed streams

Mixed fine chemical waste streams must be assessed for SVHC and CMR substance content under REACH before classification. Self-classification by producer using substance composition data. Mirror EWC entries require analytical evidence for non-hazardous designation.

ADR — Transport of hazardous chemical waste

Fine chemical waste shipped in drums or IBCs classified under ADR Class 3 (flammable liquid), 6.1 (toxic) or 8 (corrosive) as appropriate. Packing group I/II for high-hazard streams. Mixed waste streams require compatibility assessment before bulking for transport.

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Industries That Use This Waste

Sectors that valorise EWC 07 07 as an input material or secondary raw material.

Explore EU waste flows — Waste Atlas

Visualise 17 years of E-PRTR industrial facility data. See how EWC 07 07 and related waste streams flow across European industries and sectors.

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Source: EUR-Lex Commission Decision 2000/532/EC · NACE Rev.2 — Eurostat 2008

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