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Chapter 06 — Wastes from inorganic chemical processes Non-Hazardous

EWC Code

06 04

Wastes containing metals other than those mentioned in 06 03

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume

~200–600 kt/year metal-bearing residues from inorganic chemical production

Valorisation Range

Secondary metal recovery value €100–2000/t depending on precious or specialty metal content

Primary Route

Precious and specialty metal recovery

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Waste Classification

EWC 06 04 covers solid and semi-solid metal-bearing wastes from inorganic chemical manufacturing that do not fit the salt/solution classification of 06 03. Sub-codes 06 04 03* (arsenic), 06 04 04* (mercury), 06 04 05* (other heavy metals) are hazardous. Sub-code 06 04 99 covers non-hazardous metal-containing wastes not elsewhere specified.

Key streams include spent vanadium-pentoxide catalysts from sulphuric acid contact processes, spent molybdenum-based catalysts from hydrodesulphurisation, mercury-containing wastes from chlor-alkali amalgam cells (now phased out under the Mercury Regulation), and arsenic trioxide residues from non-ferrous smelting by-product processing.

Precious and platinum-group metal (PGM) catalyst waste commands significant secondary value — rhodium, palladium and platinum recovered by specialist refinery smelting. Vanadium and molybdenum catalysts are recycled through dedicated hydrometallurgical routes. Mercury recovery from 06 04 04* waste is mandatory under the EU Mercury Regulation 2017/852 before any disposal.

Typical Generators

Catalyst manufacturers
Pigment and specialty chemical plants
Electrochemical process operators

Disposal & Valorisation Routes

Established valorisation pathways for EWC 06 04, ranked by economic value and market depth. Precious and specialty metal recovery is the primary route.

Precious and specialty metal recovery

Primary

Spent PGM, vanadium and molybdenum catalysts smelted at specialist secondary refineries. Material assayed before acceptance. PGMs recovered by fire assay + wet chemistry; vanadium leached and precipitated as ammonium metavanadate. Return credit typically covers or exceeds disposal cost.

Mercury recovery and safe storage

Secondary

Mercury-containing wastes (06 04 04*) processed through retort distillation to recover elemental mercury. Under EU Mercury Regulation 2017/852, recovered mercury must be converted to mercuric sulphide or stored permanently in salt mines — export for reuse prohibited.

Hazardous waste landfill — stabilised

Backstop

Residual arsenic, antimony and cadmium-bearing solid wastes (06 04 03*, 06 04 05*) stabilised with cement-based binder and tested to WAC before disposal at hazardous landfill. Arsenic immobilisation using ferrihydrite co-precipitation preferred where technically feasible.

These are the established routes for EWC 06 04. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of other chemical products

Catalyst manufacturers recycle spent PGM and base metal catalysts through vendor take-back schemes

02
Precious metals production

Specialist refineries recover platinum, palladium, rhodium and gold from spent catalyst and chemical waste

03
Copper production

Integrated copper smelters process arsenic-bearing residues, capturing arsenic in calcium arsenate

04
Treatment and disposal of hazardous waste

Mercury retorting and arsenic stabilisation specialist operators

Source: NACE Rev.2 — Eurostat, 2008

Regulatory Context

Key legislative frameworks governing EWC 06 04 classification, transport, and treatment.

Regulation (EU) 2017/852 on Mercury

Mercury-containing wastes (06 04 04*) must be treated to remove mercury before any disposal. Recovered mercury must be stored permanently in stabilised form (HgS) or underground; export for sale prohibited. Operators must report annual mercury waste throughput.

REACH — Arsenic and cadmium restrictions

Arsenic compounds are restricted (REACH Annex XVII entry 19 for wood preservatives) and classified as SVHCs. Cadmium in wastes subject to Regulation (EU) 494/2011 concentration limits for recycled materials. Characterisation required before offering waste-derived materials.

IED 2010/75/EU — Non-ferrous metals BREF

Arsenic capture in non-ferrous smelting (from 06 04 03* processing) governed by ELVs for As in stack emissions. Wet scrubbing or bag filter + activated carbon injection required as BAT.

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Industries That Use This Waste

Sectors that valorise EWC 06 04 as an input material or secondary raw material.

Explore EU waste flows — Waste Atlas

Visualise 17 years of E-PRTR industrial facility data. See how EWC 06 04 and related waste streams flow across European industries and sectors.

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Source: EUR-Lex Commission Decision 2000/532/EC · NACE Rev.2 — Eurostat 2008

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