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Chapter 10 — Wastes from thermal processesSub-code of EWC 10 06 Hazardous

EWC Code

10 06 06

Solid wastes from gas treatment

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume (EU)

3.6 million tonnes/year EU copper recycling

Valorisation Range

€1.2B secondary copper market

Primary Route

Slag processing and aggregate use

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EWC 10 06 06 is a specific sub-code under EWC 10 06 — Wastes from copper thermal metallurgy. The classification guidance below applies to this waste stream.

Copper thermal metallurgy generates slag, flue dust, anode slimes and refractory waste across primary smelting, converting and fire-refining operations. Primary copper smelting from concentrate produces converter slag containing 1–5% copper and significant iron, silica and sulphur values. Anode slimes from electrolytic refining contain gold, silver, platinum group metals and selenium, making them highly valuable secondary products.

Copper slag is generated in large volumes from primary smelting; EU production exceeds 2 million tonnes/year. Slow-cooled crystalline slag contains fayalite and has proven applications as abrasive blasting grit, cement substitute and road aggregate. Granulated copper slag quenched with water produces a glassy material used in concrete as supplementary cementitious material.

Flue dust from secondary smelting (10 06 03*) is classified hazardous due to lead, arsenic and antimony content from mixed scrap feeds. Environmental controls under IED require afterburning and wet scrubbing for dioxin and furan control when processing mixed copper scrap containing chlorinated plastics.

Typical Generators

Copper smelters and refineries
Brass mills
Cable and wire manufacturers
Printed circuit board recyclers
Scrap copper processors

Disposal & Valorisation Routes

Established valorisation pathways for EWC 10 06 06, ranked by economic value and market depth.

Slag processing and aggregate use

Primary

Copper slag is slow-cooled and crushed to produce abrasive grit or used as cement substitute at up to 40% clinker replacement ratio. End-of-waste status applicable in many member states for slag meeting EN 12457 leachate standards. Copper-rich slag is returned to smelter for further copper recovery.

Precious metal recovery from anode slimes

Secondary

Anode slimes containing gold (100–5000 ppm), silver (5–30%), platinum and palladium are processed in precious metals refineries via chlorination, solvent extraction and electrorefining. Selenium and tellurium recovered as by-products for solar cell and thermoelectric applications.

Hazardous treatment for contaminated fractions

Backstop

Arsenic-bearing flue dust and contaminated refractory from secondary smelting require stabilisation to meet WAC leachate limits. Portland cement stabilisation reduces arsenic leachability. Treated material disposed to hazardous landfill with 30-year monitoring requirement.

These are the established routes for EWC 10 06 06. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Copper production

Reprocess copper slag and flue dust to recover residual copper, precious metals and selenium

02
Precious metals production

Process anode slimes for gold, silver and platinum group metal recovery

03
Lime and plaster manufacture

Use granulated copper slag as supplementary cementitious material in cement production

04
Recovery of sorted materials

Process mixed copper-bearing waste streams for metal recovery

05
Other specialised construction activities

Use copper slag abrasive grit for surface preparation and blasting operations

Industries That Use This Waste

Sectors that valorise EWC 10 06 06 as an input material or secondary raw material.

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