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Chapter 05 — Wastes from petroleum refining, natural gas purification and pyrolytic treatment of coalSub-code of EWC 05 01 Hazardous

EWC Code

05 01 05*

Oil spills

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

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PrimarySpent Catalyst Metal Recovery
SecondaryThermal Desorption + Oil Recovery
BackstopPermitted Hazardous Waste Incineration

~1.2M tonnes/yr (EU refineries) · Spent catalysts: €200–2000/tonne for Pt/Pd/Mo recovery; tank sludges: €30–80/tonne treatment

Primary buyers include Manufacture of other chemical products and Manufacture of cement.

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Annual Volume (EU)

~1.2M tonnes/yr (EU refineries)

Valorisation Range

Spent catalysts: €200–2000/tonne for Pt/Pd/Mo recovery; tank sludges: €30–80/tonne treatment

Primary Route

Spent Catalyst Metal Recovery

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EWC 05 01 05* is a specific sub-code under EWC 05 01 — Wastes from petroleum refining. The classification guidance below applies to this waste stream.

EWC Chapter 05 covers waste streams generated in the refining of crude petroleum, natural gas purification, and pyrolytic coal processing. These include tank bottom sludges, oily water separator contents, spent process catalysts, acid sludges from alkylation units, and contaminated clay from lube oil finishing.

Refinery sludges contain recoverable hydrocarbon fractions (20–60% oil by weight) alongside water and inorganic solids. Centrifugal and thermal desorption technologies recover the oil fraction for reprocessing, reducing hazardous waste volumes by 60–80% while generating a saleable hydrocarbon product.

Spent hydroprocessing and FCC catalysts contain significant concentrations of transition metals (Mo, Ni, V, Co, W) deposited during operation. These are the highest-value fraction in refinery waste, processed by specialist catalyst recyclers (BASF, Umicore) to recover metals as secondary raw materials for catalyst re-manufacture.

Typical Generators

Crude oil refineries
Petrochemical complexes
Natural gas processing plants
Bitumen and asphalt production facilities

Disposal & Valorisation Routes

Established valorisation pathways for EWC 05 01 05*, ranked by economic value and market depth.

Spent Catalyst Metal Recovery

Primary

Spent hydroprocessing (HDS/HDN) and fluid catalytic cracking (FCC) catalysts processed by specialist recyclers via hydrometallurgical or pyrometallurgical routes to recover Mo, Ni, V, Co, W. Recovery efficiencies: Mo 90–95%, V 85–92%, Ni 80–88%. Gate fee: negative (recycler pays for high-grade spent catalysts).

Thermal Desorption + Oil Recovery

Secondary

Oily sludges from tank bottoms and API separators processed by thermal desorption at 300–500°C to recover hydrocarbon fraction (25–55% of feed). Recovered oil returned to crude unit or sold as secondary fuel. Residual solid (<1% oil) co-processed in cement kilns. Gate fee: €40–80/tonne input sludge.

Permitted Hazardous Waste Incineration

Backstop

Non-recoverable fractions (acid sludges, contaminated clay) incinerated in permitted high-temperature hazardous waste incinerators meeting IED Directive Chapter IV emission standards. Gate fee: €150–400/tonne.

These are the established routes for EWC 05 01 05*. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of other chemical products

Catalyst metal recovery (Mo, Ni, V, Co, W) from spent catalysts

02
Manufacture of cement

Co-processing of desorbed sludge residuals as raw meal substitute

03
Treatment and disposal of hazardous waste

Incineration and stabilisation of non-recoverable acid sludge fractions

04
Manufacture of refined petroleum products

Re-blending of recovered hydrocarbon oil back into refinery crude units

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Recovery tiers only. For numbers that survive a technical review, see the validation dossier.