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Chapter 07 — Wastes from organic chemical processesSub-code of EWC 07 06 Non-Hazardous

EWC Code

07 06 11

Sludges from on-site effluent treatment not containing dangerous substances

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume (EU)

~500 kt–1.5 Mt/year across soap, detergent and cosmetics manufacturing

Valorisation Range

Glycerol by-product €300–500/t; fatty acid distillation residues €50–150/t as feed

Primary Route

Oleochemical by-product valorisation

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EWC 07 06 11 is a specific sub-code under EWC 07 06 — Wastes from manufacture, formulation, supply and use of fats, grease, soaps, detergents, disinfectants and cosmetics. The classification guidance below applies to this waste stream.

EWC 07 06 covers wastes from oleochemical processing, soap and detergent manufacture, disinfectant production, and cosmetics manufacturing. Most sub-codes are non-hazardous given the biological origin of feedstocks, but 07 06 01* (aqueous washing liquids and mother liquors), 07 06 03* (halogenated solvents) and 07 06 07* (halogenated still bottoms) are hazardous where dangerous substances are present.

Oleochemical refining generates soap stock (alkali-refined — contains soaps, phospholipids and water), spent bleaching earth (SBE — activated clay saturated with vegetable oil), and fatty acid distillation residues (pitch). Soap stock acidulation produces acid oil for biodiesel or animal feed. SBE retains 20–35% oil and is combusted for energy recovery or composted if oil content is sufficiently low.

Detergent manufacture generates surfactant mother liquors (high COD, anionic/non-ionic surfactant content), spray-drying scrubber water and filter press cake from silicate/zeolite slurry systems. Cosmetics production creates solvent-based residues from fragrance formulation and small volumes of out-of-specification product. Glycerol from biodiesel and soap production is a high-volume by-product with established markets in food, pharmaceutical and industrial applications.

Typical Generators

Oleochemical producers (FAME, fatty acids)
Soap and detergent manufacturers
Personal care and cosmetics plants

Disposal & Valorisation Routes

Established valorisation pathways for EWC 07 06 11, ranked by economic value and market depth.

Oleochemical by-product valorisation

Primary

Soap stock acidulated to acid oil and sold for biodiesel (FAME), animal feed or oleochemical feedstock. Glycerol purified and sold to pharmaceutical, food or chemical sectors. Fatty acid pitch used as fuel for steam raising on-site. SBE with >15% oil co-processed at cement kiln or combusted.

Biological effluent treatment for surfactant waste

Secondary

Aqueous washing liquids and mother liquors with high COD (2000–20000 mg/L) treated by activated sludge biological treatment. Surfactant-containing streams require extended aeration for full mineralisation. Treated effluent monitored for anionic surfactant concentration before discharge to sewer.

Incineration and composting of SBE

Backstop

Spent bleaching earth with low oil content (≤10%) composted with other bio-waste fractions — clay minerals act as soil conditioner. High-oil SBE (>20%) co-incinerated at permitted facilities. All SBE disposal avoids landfill of oily material under IED permit conditions.

These are the established routes for EWC 07 06 11. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of soap and detergents

Generates 07 06 streams; glycerol and fatty acid by-products sold to multiple sectors

02
Manufacture of oils and fats

Oleochemical refiners generate soap stock and SBE as by-products from vegetable oil refining

03
Manufacture of other organic basic chemicals

Oleochemicals (fatty acids, fatty alcohols) from acid oil serve as base chemicals for surfactant synthesis

04
Treatment and disposal of non-hazardous waste

Biological treatment of surfactant-bearing effluent; composting of SBE

Industries That Use This Waste

Sectors that valorise EWC 07 06 11 as an input material or secondary raw material.

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