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Chapter 06 — Wastes from inorganic chemical processesSub-code of EWC 06 10 Hazardous

EWC Code

06 10 02*

Wastes containing dangerous substances from nitrogen chemical processes

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume (EU)

~500 kt–1 Mt/year nitrogen process wastes EU-wide

Valorisation Range

Off-spec ammonium nitrate destruction cost €150–400/t; ammonia recovery significant where feasible

Primary Route

Ammonia recovery and SCR NOx reduction

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EWC 06 10 02* is a specific sub-code under EWC 06 10 — Wastes from manufacture, formulation, supply and use of nitrogen chemicals, nitrogen chemical processes and manufacture of fertilisers. The classification guidance below applies to this waste stream.

EWC 06 10 covers wastes from nitrogen chemical processes including ammonia synthesis, nitric acid production and nitrogen fertiliser manufacture. Sub-code 06 10 02* (wastes containing dangerous substances) is hazardous. Non-hazardous nitrogen wastes (06 10 02 mirror) arise from aqueous streams with low NH₃ or NOₓ contamination.

The principal waste challenge in this chapter is off-specification ammonium nitrate (AN) — a material with significant explosive risk. EU Regulation 2003/2003 on fertilisers and COMAH Directive 2012/18/EU impose strict controls on AN storage and handling. Off-spec AN arising from production upsets must be destroyed rather than landfilled, using high-temperature decomposition or dissolution followed by wastewater treatment.

Ammonia purge gas from Haber-Bosch synthesis is recovered and recycled to the converter; but blowdown streams containing inerts (methane, argon) also carry ammonia that must be scrubbed. Nitric acid tail gas contains residual NOₓ which is reduced by SCR (selective catalytic reduction) or extended absorption. Catalyst wastes (Fe, Pt/Rh gauze from nitric acid burners) have significant secondary precious metal value.

Typical Generators

Ammonia synthesis plants (Haber-Bosch)
Nitric acid producers
Ammonium nitrate fertiliser plants

Disposal & Valorisation Routes

Established valorisation pathways for EWC 06 10 02*, ranked by economic value and market depth.

Ammonia recovery and SCR NOx reduction

Primary

Ammonia-containing purge gases scrubbed with water or dilute acid to recover ammonium salt. Ammonia solution returned to fertiliser production or sold as aqueous ammonia. NOₓ tail gas treated by selective catalytic reduction (SCR) to convert NOₓ to N₂ and H₂O.

Off-spec ammonium nitrate destruction

Secondary

Off-specification AN dissolved in excess water (>5:1 water:AN ratio below COMAH thresholds) and discharged to biological effluent treatment as dilute ammonium nitrate wastewater. Alternatively decomposed thermally at >200°C in controlled furnace. Disposal to landfill prohibited for AN.

Catalyst precious metal recovery

Backstop

Spent Pt/Rh gauze catalysts from nitric acid burners returned to platinum group metal refiners under supplier take-back. Fe-based ammonia synthesis catalysts recovered for iron content. Precious metal value typically covers recovery and refining costs.

These are the established routes for EWC 06 10 02*. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Manufacture of fertilisers and nitrogen compounds

Generates the majority of nitrogen chemical waste; closed-loop recovery is BAT

02
Treatment and disposal of non-hazardous waste

Biological nitrogen removal from ammonium-containing effluents

03
Precious metals production

Recovers platinum and rhodium from spent nitric acid catalyst gauze

04
Treatment and disposal of hazardous waste

Handles COMAH-classified AN waste streams requiring specialist destruction

Industries That Use This Waste

Sectors that valorise EWC 06 10 02* as an input material or secondary raw material.

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