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Chapter 16 — Wastes not otherwise specified in the listSub-code of EWC 16 09 Hazardous

EWC Code

06 03 13

Solid salts and solutions containing heavy metals

EUR-Lex Commission Decision 2000/532/EC — Official Journal L 226, 06/09/2000

Annual Volume (EU)

50,000 tonnes/year EU-wide

Valorisation Range

Specialist disposal; limited recovery market

Primary Route

Chemical reduction and neutralisation

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EWC 06 03 13 is a specific sub-code under EWC 16 09 — Oxidising substances. The classification guidance below applies to this waste stream.

EWC 16 09 covers oxidising substances not otherwise classified. Entry 16 09 01* (permanganates, e.g. potassium permanganate), 16 09 02* (chromates, e.g. potassium chromate, potassium dichromate), 16 09 03* (peroxides, e.g. hydrogen peroxide), 16 09 04* (other oxidising substances not otherwise specified) all carry hazardous designation.

Oxidising waste substances react exothermically with organic materials, fuels and reducing agents. Contamination of oxidising waste with organic matter constitutes a fire and explosion hazard. Storage and handling must segregate oxidising wastes from combustibles, reducing agents and incompatible chemicals.

Chromate-containing wastes are subject to restriction under REACH Annex XVII (hexavalent chromium) and require specific treatment — typically reduction to Cr(III) followed by hydroxide precipitation — before disposal. Permanganate wastes may be reduced to MnO2 for stabilisation. Peroxide waste decomposition must be controlled to prevent oxygen evolution.

Typical Generators

Chemical manufacturers
Laboratories
Bleaching and textile processors
Water treatment plants
Pharmaceutical producers

Disposal & Valorisation Routes

Established valorisation pathways for EWC 06 03 13, ranked by economic value and market depth.

Chemical reduction and neutralisation

Primary

Chromate wastes reduced from Cr(VI) to Cr(III) using reducing agents (sodium metabisulphite, SO2); precipitated as Cr(OH)3. Permanganate reduced to MnO2. Neutralised, precipitated sludges dewatered for hazardous landfill.

Controlled decomposition (peroxides)

Secondary

Hydrogen peroxide waste solutions diluted and decomposed catalytically (MnO2 catalyst or heating) to water and oxygen under controlled ventilation. Diluted solutions may be suitable for wastewater treatment as oxidant.

High-temperature incineration

Backstop

Mixed oxidising waste streams not amenable to chemical treatment incinerated at permitted high-temperature facility. Excess oxygen from oxidisers must be accounted for in combustion air calculation. Dedicated oxidiser waste streams may be used as combustion air supplement.

These are the established routes for EWC 06 03 13. Which one your stream qualifies for depends on its composition, volume and region.

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NACE Receiving Industries

Primary & secondary off-takers

01
Hazardous waste treatment

Licensed chemical treatment and disposal of chromate, permanganate and peroxide wastes

02
Industrial gases manufacture

Recovery of oxygen from controlled peroxide decomposition where concentrations justify

03
Water collection, treatment and supply

Dilute hydrogen peroxide waste used as oxidant in water treatment processes

04
Manufacture of other chemical products

Re-formulation of off-spec oxidising substances where composition allows

Industries That Use This Waste

Sectors that valorise EWC 06 03 13 as an input material or secondary raw material.

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